\documentstyle[paasms,pptwocol]{preprint} \def \um {\ifmmode \mu \hbox{m}\else $\mu $m\fi } \input pub.sty \begin{document} \title{TITAN'S 5 \protect\boldmath{$\mu$}m SPECTRAL WINDOW:\\ ~\\ CARBON MONOXIDE AND THE ALBEDO OF THE SURFACE} \author{Keith S.~Noll\\ \\ Space Telescope Science Institute\\ 3700 San Martin Drive\\ Baltimore, MD 21218\\ phone: 410-338-1828, fax: 410-338-4767, email: noll@stsci.edu\\ \and Thomas R.~Geballe\\ \\ Joint Astronomy Centre\\ 660 N.~A'ohoku Place\\ University Park, Hilo, HI 96720\\ \and Roger F.~Knacke\\ \\ The Pennsylvania State University\\ Erie, PA 16563\\ \and Yvonne J.~Pendleton\\ \\ NASA Ames Research Center\\ MS 245-3\\ Moffett Field, CA, 94035} \pub{Icarus} \recacc{7 May 1996}{27 August 1996} \maketitle \abstract{ We have measured the spectrum of Titan near 5~\um\ and have found it to be dominated by absorption from the carbon monoxide 1-0 vibration-rotation band. The position of the band edge allows us to constrain the abundance of CO in the atmosphere and/or the location of the reflecting layer in the atmosphere. In the most likely case, 5~\um\ radiation is reflected from the surface and the mole fraction of CO in the atmosphere is qCO = 10~${+10\atop -5}$ ppm, significantly lower than previous estimates for tropospheric CO. The albedo of the reflecting layer is approximately 0.07~${+0.02\atop -0.01}$ in the 5~\um\ continuum outside the CO band. The 5~\um\ albedo is consistent with a surface of mixed ice and silicates similar to the icy Galilean satellites. Organic solids formed in simulated Titan conditions can also produce similar albedos at 5~\um.}